potassium t-butoxide CAS# 865-47-4
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Chemical Name: potassium t-butoxide
CAS No.: 865-47-4
Molecular FormulaC4H9KO
Average mass212
Appearance: white crystalline powder
Sample: Available

potassium t-butoxide : The Complete Guide
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Description of potassium t-butoxide
Potassium tert-butoxide is the chemical compound with the formula K+(CH3)3CO−. This colourless solid is a strong base (pKa of conjugate acid around 17) which is useful in organic synthesis. It exists as a tetrameric cubane-type cluster. It is often seen written in chemical literature as potassium t-butoxide.
Basic Info of potassium t-butoxide
Chemical Name | Potassium tert-butanolate |
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Synonyms | |
CAS No. | 865-47-4 |
Molecular Formula | C4H9KO |
Molecular Weight | 112.21200 |
PSA | 23.06000 |
LogP | 1.21540 |
Safety Info
Hazard Class | 8 |
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Safety Statements | S16-S33-S36/37/39-S43-S8 |
HS Code | 29051900 |
WGK Germany | 1 |
Packing Group | I |
RIDADR | UN 3274 3/PG 2 |
Risk Statements | R11; R14; R19; R35 |
Hazard Codes | C |
Supplemental Hazard Statements | May form explosive peroxides; Reacts violently with water. |
Caution Statement | P210; P231 + P232; P280; P370 + P378; P402 + P404; P403 + P235 |
Hazard Declaration | H225; H260; H302; H314; H335; H351 |
Symbol | GHS02, GHS05, GHS07, GHS08 |
Signal Word | Danger |
Properties
Appearance & Physical State | white crystalline powder |
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Density | 0.929 |
Boiling Point | 275ºC |
Melting Point | 256-258ºC |
Flash Point | -21ºC |
Water Solubility | REACTS |
Stability | Stable, but reacts violently with water and acids, possibly leading to fire. Incompatible with water, acids, halogenated hydrocarbons, alcohols, strong oxidizing agents, ketones, carbon dioxide. |
Storage Condition | Flammables area |
Vapor Pressure | 1 mm Hg ( 220 °C) |
Numbering system
MDL number | MFCD00012162 |
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What is potassium t-butoxide ?
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The official answer: Ambroxan is a chemical compound with a relative molecular weight of 236.34.
What’s the application of potassium t-butoxide ?
Potassium tert-butoxide, an organic compound with the molecular formula C4H9OK, is an important organic base with a higher basicity than potassium hydroxide. Due to the induction effect of (CH3)3CO- three methyl groups, it has stronger basicity and activity than other potassium alcohols, so it is a good catalyst. In addition, as a strong base, potassium tert-butoxide is widely used in chemical, pharmaceutical, pesticide and other organic synthesis, such as ester exchange, condensation, rearrangement strength, polymerization, ring opening and the production of heavy metal protic acid esters.
Conclusion
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